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The use of PhSeCl in the synthesis of cyclic ethers

โœ Scribed by K.C. Nicolaou; Zenon Lysenko


Book ID
104244106
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
181 KB
Volume
18
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Our recent introduction of certain selenium reagents to induce cyclization reactions efficiently and under extremely mild conditions, 1 opened up a variety of promising avenues for the synthesis of heterocycles. We now wish to report


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Fluorinative ring-expansion of cyclic et
โœ Tomotake Inagaki; Yutaka Nakamura; Masanori Sawaguchi; Norihiko Yoneda; Shinichi ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 213 KB

Fluorinated five-to seven-membered cyclic ethers were stereoselectively synthesized from four-to six-membered cyclic ethers having an iodoalkyl substituent by fluorinative ring-expansion reaction using p-iodotoluene difluoride.