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The Use of Phosphazenes as Fire Resistant Materials

✍ Scribed by Allen, C. W.


Book ID
121351723
Publisher
SAGE Publications
Year
1993
Tongue
English
Weight
421 KB
Volume
11
Category
Article
ISSN
0734-9041

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Azidophosphanes are versatile reactants in the Staudinger reaction. The azides Cl2PN3 (I), (Et2N)ClPN3 (2), and (Et2N)2PN3 (3) react with phosphanes to give the N-phosphanyl phosphazenes 4-10. (Et2N)P(N3), is oxidized by PhN, yielding (Et2N)P(N3),=NPh (1 I), which with PPh3 yields the di-and triphos