The use of normal pulse polarography in the study of electrode kinetics
β Scribed by J.H. Christie; E.P. Parry; R.A. Osteryoung
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- English
- Weight
- 323 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
β¦ Synopsis
The equations of Barker for normal pulse polarography have been applied to the study of the kinetics of Zn(II) reduction in NaN08. Results in good agreement with literature are obtained. Rhm16-011 applique les equations de Barker pour la polarographie normale a pulsations a la cinetique de la reduction du Zn(II) en solution de NaNO s. Les n%ultats obtenus sont en bon accord aveo eeux de la litterature. B-Die Rarker'sehen Gleichungen ftlr die normale Impulspolarographie wurden bei einer Untersuchung der Kinetik der Zn(II)-Reduktion in NaNOI verwendet. Man erhiilt Ergebnisse, welche sehr gut mit den Literaturdaten tibereinstimmen. PULSE polarography was originally developed as a trace analytical technique,l but
π SIMILAR VOLUMES
Two types of complex curves are discussed: I) those obtained for binary mixtures of substances reducing at similar potentials and 11) those corresponding to the two-electron consecutive processes: 0 -t Z -R and 0 $ 2 -+ R. A convenient procedure of curve fitting for the above two cares of complex no
## Abstract Components of the net response in differential pulse polarography were studied theoretically, assuming gradually changing electrode rate constant or strength of the reactant adsorption. The difference between the maximum potential of the peak component and the halfβwave potential of the