✦ LIBER ✦

The use of MFe3S4 clusters (M = Mo, V) and derivatives in the reduction of nitrogenase substrates

✍ Scribed by D. Coucouvanis; K.D. Demadis; L.J. Laughlin; S.M. Malinak; P.E. Mosier

Book ID: 103570662
Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 75 KB
Volume: 59
Category: Article
ISSN: 0162-0134
DOI: 10.1016/0162-0134(95)97813-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Metal Substitution in the Active Site of

Metal Substitution in the Active Site of Nitrogenase MFe 7 S 9 (M = Mo 4+ , V 3+ , Fe 3+ )

✍ Lovell, Timothy; Torres, Rhonda A.; Han, Wen-Ge; Liu, Tiqing; Case, David A.; No 📂 Article 📅 2002 🏛 American Chemical Society 🌐 English ⚖ 231 KB

Catalytic and stoichiometric multielectr

Catalytic and stoichiometric multielectron reduction of hydrazine to ammonia and acetylene to ethylene with clusters that contain the MFe3S4 cores (MMo, V). Relevance to the function of nitrogenase

✍ Dimitri Coucouvanis; Konstantinos D. Demadis; Steven M. Malinak; Patrick E. Mosi 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 962 KB

A functional model for nitrogenase is currently sought in our laboratory in reactivity studies using various single cubane clusters that possess the [ MFe3S4]" + core, (M = Mo, n = 3; M = V, n = 2). These clusters are used as catalysts for the reduction of enzymatically relevant substrates. Substrat

Synthesis and structure of the organomet

Synthesis and structure of the organometallic MFe2(�3-S)2 clusters (M = Mo or Fe)

✍ Han, Jaehong; Coucouvanis, Dimitri 📂 Article 📅 2005 🏛 Royal Society of Chemistry 🌐 English ⚖ 214 KB

Catalytic Reduction of cis -Dimethyldiaz

Catalytic Reduction of cis -Dimethyldiazene by the [MoFe 3 S 4 ] 3+ Clusters. The Four-Electron Reduction of a NN Bond by a Nitrogenase-Relevant Cluster and Implications for the Function of Nitrogenase

✍ Malinak, Steven M.; Simeonov, Anton M.; Mosier, Patrick E.; McKenna, Charles E.; 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 176 KB

New Fe/Mo/S Clusters with MoFe 3 S 3 Cub

New Fe/Mo/S Clusters with MoFe 3 S 3 Cuboidal Cores Similar to the One in the Fe/Mo Cofactor of Nitrogenase. Synthesis and Structural Characterization of the (C1 4 -cat)MoFe 3 S 3 (PEt 3 ) 2 (CO) 6 and (C1 4 -cat)Mo(O)Fe 3 S 3 (PEt 3 ) 3 (CO) 5 Clusters

✍ Tyson, Marni A.; Coucouvanis, Dimitri 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 79 KB

Synthesis of MFe 3 S 4 Clusters Containi

Synthesis of MFe 3 S 4 Clusters Containing a Planar M II Site (M = Ni, Pd, Pt), a Structural Element in the C-Cluster of Carbon Monoxide Dehydrogenase

✍ Panda, Rashmishree; Berlinguette, Curtis P.; Zhang, Yugen; Holm, Richard H. 📂 Article 📅 2005 🏛 American Chemical Society 🌐 English ⚖ 628 KB