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The unusual formation of phenanthrene during the methylation of benzo[h]quinoline 1-oxide with methylsulfinyl carbanion.

✍ Scribed by Y. Hamada; I. Takeuchi; M. Hirota


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
97 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis


The methylsulfinyl carbanlon has been recognized as an efficient methylating


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## Abstract Reduction of the isoprene—PCl~3~ adduct 1 with magnesium powder, or with Si~2~Cl~6~, furnished __P__‐chloro‐3‐methyl‐phosphol‐2‐ene, 2, in satisfactory yield. Further reduction of 2 with Si~2~Cl~6~ gave the new trichlorosilyl‐3‐methylphosphol‐2‐ene, 3. The reaction of 2 with magnesium p