Unusual Ring-Closure Reactions During th
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Vollbrecht, Sebastian ;Vollbrecht, Alexander ;Jeske, Jörg ;Jones, Peter G. ;Schm
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Article
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1997
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Wiley (John Wiley & Sons)
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English
⚖ 426 KB
👁 2 views
## Abstract Reduction of the isoprene—PCl~3~ adduct 1 with magnesium powder, or with Si~2~Cl~6~, furnished __P__‐chloro‐3‐methyl‐phosphol‐2‐ene, 2, in satisfactory yield. Further reduction of 2 with Si~2~Cl~6~ gave the new trichlorosilyl‐3‐methylphosphol‐2‐ene, 3. The reaction of 2 with magnesium p