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ChemInform Abstract: Unusual Ring-Closure Reactions During the Oxidation of 1,1′-Bi(3- methylphosphol-2-ene) with Hexafluoroacetone - Formation of a Tricyclic Fluorine-Containing Phosphorane.

✍ Scribed by S. VOLLBRECHT; A. VOLLBRECHT; J. JESKE; P. G. JONES; R. SCHMUTZLER; W.-W. DU MONT


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract Reduction of the isoprene—PCl~3~ adduct 1 with magnesium powder, or with Si~2~Cl~6~, furnished __P__‐chloro‐3‐methyl‐phosphol‐2‐ene, 2, in satisfactory yield. Further reduction of 2 with Si~2~Cl~6~ gave the new trichlorosilyl‐3‐methylphosphol‐2‐ene, 3. The reaction of 2 with magnesium p

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v