## Abstract Reduction of the isoprene—PCl~3~ adduct 1 with magnesium powder, or with Si~2~Cl~6~, furnished __P__‐chloro‐3‐methyl‐phosphol‐2‐ene, 2, in satisfactory yield. Further reduction of 2 with Si~2~Cl~6~ gave the new trichlorosilyl‐3‐methylphosphol‐2‐ene, 3. The reaction of 2 with magnesium p
✦ LIBER ✦
ChemInform Abstract: Unusual Ring-Closure Reactions During the Oxidation of 1,1′-Bi(3- methylphosphol-2-ene) with Hexafluoroacetone - Formation of a Tricyclic Fluorine-Containing Phosphorane.
✍ Scribed by S. VOLLBRECHT; A. VOLLBRECHT; J. JESKE; P. G. JONES; R. SCHMUTZLER; W.-W. DU MONT
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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