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The unimolecular decomposition of vibrationally excited 1-deuterio-1,1,2-trifluoroethane

✍ Scribed by D. W. Follmer; G. O. Pritchard

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
693 KB
Volume
6
Category
Article
ISSN
0538-8066

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✦ Synopsis

A srudy has been made of the unimolecular decomposition of the vibrationally excited molecule CFZDCFHz*, formed from the combination of CFzD and CFH? radicals. The a,B-elirnination channels lead to the products cisand trans-CFDCFH and CFzCHz and H(D)F. The a,a-elimination channel produces cisand trans-CFHCFH and DF. The pressure dependencies of the various isomer ratios have been examined. For the a,a elimination the energy partitioning pattern is such that subsequent isomerization of the olefin product can occur. This, and previous work on CDClZCHZCl*, clearly show that the enrrgy partitioning in a,a and a,@ eliminations is very different. It is tentatively concluded that HF (from the CFH? group) and HD eliminations also take place.

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