The thermal, unimolecular elimination of HF from CH3CF3 was studied by three different groups over the temperature range 1000" to 1800°K. While the reported kinetic parameters varied greatly, it is shown here that these data may be satisfactorily correlated in terms of a four-center transition state
Recalculation of data on the thermal decomposition of 1,1-difluoroethane and 1,1,1-trifluoroethane
✍ Scribed by Wing Tsang
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 319 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Abstract
Disagreements in rate constants and parameters between published results on the decomposition of 1,1‐difluoroethane and 1,1,1‐trifluoroethane are shown to originate from incorrect specification and setting of reaction conditions in one of the studies. When corrected, applicable results are in excellent agreement.
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