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The unanimity rule revisited: the case of revisions of hybrid constitutions

✍ Scribed by Christian Kirchner

Book ID
118808810
Publisher
Springer US
Year
2012
Tongue
English
Weight
191 KB
Volume
152
Category
Article
ISSN
0048-5829

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The reaction mechanism of the LiH addition to Ξ±-chiral ketones and acylsilanes was calculated at the ab initio MP2/6-311+G\*\*//RHF/6-31G\* level. The selectivities predicted on the basis of the computed transition states and reaction barriers compare well with the experimental data. For compounds p