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The triplet state of magnesiumporphin · ethanol in an n-octane crystal studied by microwave induced changes in the fluorescence intensity

✍ Scribed by G. Jansen; J.H. van der Waals

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 381 KB
Volume: 43
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80589-1

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✦ Synopsis

The zero-flcld cphtting of the triplet \tnte of mqncsmmporphin solvatcd by ethzmol is rcprcsented by D = 0.035 cm-t and KI = 0.010 cm-'. The decay rates of the upper two spin componenti both nre found to be about 20 s-~, while that of the bottom component (where the spin lict in the molecular plane) IS about 2 s-l.

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