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Investigation of the lowest triplet state of free base porphin by microwave induced changes in its fluorescence

✍ Scribed by W.G. Van Dorp; T.J. Schaafsma; M. Soma; J.H. Van Der Waals

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 434 KB
Volume: 21
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)80123-x

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✦ Synopsis

The zero-field splitting of the non-phosphorescent lowest tiplet state of free base por;lhh is mea_quEd by ob_ serving microwave induced &axes in the fluorescence of this molecule as agliest in a Shpolskii-matrix ofn-ocae at 4.2%.

The doublet character of the fluorescence spectrum of the system also manifests itself in the microwave Spectruik

It is proved that this doublet structure is caused by two physi&Iy distinct free base paqhin molecules in the host lattice.

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