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The Triple Role of Fluoride Ions in Palladium-Catalyzed Suzuki–Miyaura Reactions: Unprecedented Transmetalation from [ArPdFL2] Complexes

✍ Scribed by Dr. Christian Amatore; Dr. Anny Jutand; Gaëtan Le Duc


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
458 KB
Volume
51
Category
Article
ISSN
0044-8249

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Kinetic Data for the Transmetalation/Red
✍ Dr. Christian Amatore; Dr. Anny Jutand; Gaëtan Le Duc 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB 👁 1 views

## Dedicated to Professor Marc Julia , which generates ArAr' and a Pd 0 species. Conversely, the base OH À disfavors the reaction by formation of the unreactive anionic Ar'B(OH) 3 À . As a consequence of these antagonistic effects of OH À , the overall reactivity is controlled by the concentratio