The Trinuclear Gallium-Bridged Ferrocenophane [{Fe(η5-C5H4)2}3Ga2]: Synthesis, Bonding, Structure, and Coordination Chemistry
✍ Scribed by Alexander Althoff; Dirk Eisner; Peter Jutzi; Norman Lenze; Beate Neumann; Wolfgang W. Schoeller; Hans-Georg Stammler
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 397 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
40°C. Slow warm-up to room temperature, column chromatographic work-up (silica gel flash chromatography, elution with a 10 : 1 : 1 mixture of dichloromethane, petroleum ether (30-50°C) and diethyl ether), and Kugelrohr distillation (bath temperature 45 "C at 0.1 torr) afforded the a-methylene-p-lact
## Abstract The reaction of the title cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe—Fe bond to afford bis‐sodium salt (Me~2~SiSiMe~2~) [η^5^‐C~5~H~4~Fe (CO)~2~Na]~2~ (4). The latter was not isolated and was used directly to react with MeI, PhCH~2~Cl, CH~3