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The triclinic-tetragonal phase transition of octaethylporphinatonickel(II)

✍ Scribed by W. Scheuermann; K. Nakamoto


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
284 KB
Volume
48
Category
Article
ISSN
0022-2860

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Phase Transition from the Cubic Zintl Ph
✍ Helmut Ehrenberg; Hermann Pauly; Thomas Hansen; Jean-Christophe Jaud; Hartmut Fu πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 247 KB

The binary face-centered cubic Zintl phase LiIn (NaTl-type, B32 in the classification of the ''Strukturberichte'') undergoes a tetragonal distortion from Fd % 3m into I4 1 =amd. This phase transition is reversible and ''translationengleich''. The transition temperature of 170(10) K was determined ba