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Phase Transition from the Cubic Zintl Phase LiIn into a Tetragonal Structure at Low Temperature

✍ Scribed by Helmut Ehrenberg; Hermann Pauly; Thomas Hansen; Jean-Christophe Jaud; Hartmut Fuess


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
247 KB
Volume
167
Category
Article
ISSN
0022-4596

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✦ Synopsis


The binary face-centered cubic Zintl phase LiIn (NaTl-type, B32 in the classification of the ''Strukturberichte'') undergoes a tetragonal distortion from Fd % 3m into I4 1 =amd. This phase transition is reversible and ''translationengleich''. The transition temperature of 170(10) K was determined based on X-ray and neutron powder diffraction data.