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The triazene method for the deamination of aliphatic amines

✍ Scribed by Emil H. White; Hanspeter Scherrer

Publisher
Elsevier Science
Year
1961
Tongue
French
Weight
224 KB
Volume
2
Category
Article
ISSN
0040-4039

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✦ Synopsis

TWO general methods for the deamination of primary aliphatic amines, the nitrous acid-amine reaction1 and the nitrosoamide decomposition, 2 have been reported in the chemical literature. We would like to call attention to a third method which we have found to be useful for the conversion of primary amines into esters, alkyl halides, ethers, and related derivatives. This method, suggested by work on the reaction of nitrosyl chloride with aliphatic amines, 3 involves triazene intermediates as outlined in equation (1).

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