## Abstract The ruthenium(II) and rhenium(I) complexes containing an NAD(P)H model compound, 1‐benzyl‐1,4‐dihydronicotinamide (BNAH), as ligand, [Ru(tpy)(bpy)(BNAH)]^2+^ (1 a) and [Re(bpy)(CO)~3~(BNAH)]^+^ (1 b), were quantitatively produced by the reaction of the corresponding metal hydrido comple
✦ LIBER ✦
The transition state in the reduction of ketones by complex metal hydrides. Reassessment and limited reincarnation of the concept of product development control.
✍ Scribed by Donald C. Wigfield; Frederick W. Gowland
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 204 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Using the conclusion of the previous communication, and other data, it is concluded that NaBHI, reductions involve and product-like transition state and LiAIHI, reductions involve a reactant-like transition state.
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