✦ LIBER ✦

The Energy Profile of Proton Transfer from Brønsted Acids to Terminal Hydrides in Transition Metal Complexes Can Be Estimated by Combining in situ IR and NMR Spectroscopy

✍ Scribed by Natalia V. Belkova; Ekaterina V. Bakhmutova; Elena S. Shubina; Claudio Bianchini; Maurizio Peruzzini; Vladimir I. Bakhmutov; Lina M. Epstein

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 229 KB
Volume: 2000
Category: Article
ISSN: 1434-1948
DOI: 10.1002/1099-0682(200010)2000:10<2163::aid-ejic2163>3.0.co;2-#

No coin nor oath required. For personal study only.

✦ Synopsis

The enthalpy and entropy changes relative to the stepwise reaction of [(triphos)Re(CO) 2 H] with perfluoro-tert-butyl alcohol in CH 2 Cl 2 to give first the hydrogen-bonded adduct [(triphos)Re(CO) 2 H•••HOC(CF 3 ) 3 ] and then the stable non-[a] A. N.