The transferability of the carbonyl group in aldehydes and ketones
✍ Scribed by Graña, Ana M.; Mosquera, Ricardo A.
- Book ID
- 118139545
- Publisher
- American Institute of Physics
- Year
- 1999
- Tongue
- English
- Weight
- 435 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.478568
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Thechemistry ofpolyfluorinatedketones has recently received a great dealof attention [1 I 21 La]. The carboriyl and imino groups of the fluorinated ketones and their imines react in many different ways. Zn particular, the electron-attracting perfluoroalkyl groups intensify the elecrrophilic properti
An investigation of the influence of angular strain on the stretching vibration of carbonyl groups fa cyclic ketones is made. The results obtsined by a normal coordinate treatment show that frequency variation is due both to kinetic energy and potential energy effects.