Hore and McLauchlan that shortly after their formation geminate isopropylketyl radicals in isopropanol at law temperature ( ~200 K) exhibit ESR spectra with "antiphase" lineshape, i.e. lines with their low-field halves in emission and high-field halves in absorption. It is shown that a theory which
The time development of the magnetic moment of correlated radical pairs
โ Scribed by Zhiyu Wang; Jau Tang; James R Norris
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 650 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0022-2364
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The ESR lineshape of spin-correlated radical pairs (RP) diffusing in a small volume is calculated within the sudden perturbation approach for space dimensionalities D = 1, 2, 3. It is shown that in 2D and 3D models the RP spin dynamics are described by a Bioch-type equation quite accurately. A simpl