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A study of the time parameters of radical geminate pairs by stroboscopic magnetic field techniques

โœ Scribed by N.L. Lavrik; V.E. Khmelinsky


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
539 KB
Volume
140
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The magnetosensitivity time for the pyrene excimer delayed fluorescence of the exciplex system pyrene-N,Ndiethylaniline in methanol was studied by pulsed magnetic field techniques. The half-life of the magnetic effect was shown to be about 40 ns. The maximum magnetosensitivity time after photoexcitation appeared to be greater than 70 ns. The values are interpreted as geminate-pair lifetimes.


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Magnetic field effect on the geminate an
โœ L.A. Margulis; I.V. Khudyakov; V.A. Kuzmin ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 369 KB

The effects of an external magnettc field (H = 2000 G) on photogenerated geminate(G) and random (F) pairs of chlorophyll a radical canon and p-benzoqumone radical anion in VISCOUS 1,3-propanediol have been measured: ac; = 8 f I%, ar = -7 k 2%. The results have been used for calculation of the probab