A study of the time parameters of radical geminate pairs by stroboscopic magnetic field techniques
โ Scribed by N.L. Lavrik; V.E. Khmelinsky
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 539 KB
- Volume
- 140
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The magnetosensitivity time for the pyrene excimer delayed fluorescence of the exciplex system pyrene-N,Ndiethylaniline in methanol was studied by pulsed magnetic field techniques. The half-life of the magnetic effect was shown to be about 40 ns. The maximum magnetosensitivity time after photoexcitation appeared to be greater than 70 ns. The values are interpreted as geminate-pair lifetimes.
๐ SIMILAR VOLUMES
The effects of an external magnettc field (H = 2000 G) on photogenerated geminate(G) and random (F) pairs of chlorophyll a radical canon and p-benzoqumone radical anion in VISCOUS 1,3-propanediol have been measured: ac; = 8 f I%, ar = -7 k 2%. The results have been used for calculation of the probab