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The Thionitrosyl Cation NS+ as a Synthetic Reagent

✍ Scribed by Dr. Rüdiger Mews

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
226 KB
Volume
15
Category
Article
ISSN
0044-8249

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✦ Synopsis

c) Allylation at the arsenic to form ( 5 ) , [3s,3s]-sigmatropic shift of the allyl group into the 3or 5-position as a hetero-Cope rearrangement to give ( 6 ) , and repetition of this reaction sequence.

Pathway (b) can be ruled out: crotyl bromide reacts with ( 1 ) to give (7) in which the crotyl moieties in positions

📜 SIMILAR VOLUMES

The [Re(CO)6]+ Cation as a Ligand-Transf
The [Re(CO)6]+ Cation as a Ligand-Transfer Reagent with Ferrocene Derivatives
✍ Siden Top; Stéphane Masi; Gérard Jaouen 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 109 KB 👁 2 views

The [Re(CO) 6 ] + cation is a stable compound, soluble in aqueous media. We show that it can be used as a reagent in the synthesis of tricarbonyl(cyclopentadienyl)rhenium complexes. [Re(CO) 6 ] + reacts with ferrocene derivatives, particularly acetylferrocene, in DMSO, DMF or a water/DMSO (1:1)