𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The [Re(CO)6]+ Cation as a Ligand-Transfer Reagent with Ferrocene Derivatives

✍ Scribed by Siden Top; Stéphane Masi; Gérard Jaouen

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
109 KB
Volume
2002
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

✦ Synopsis

The [Re(CO) 6 ] + cation is a stable compound, soluble in aqueous media. We show that it can be used as a reagent in the synthesis of tricarbonyl(cyclopentadienyl)rhenium complexes. [Re(CO) 6 ] + reacts with ferrocene derivatives, particularly acetylferrocene, in DMSO, DMF or a water/DMSO (1:1)

📜 SIMILAR VOLUMES

Silver Compounds in Synthetic Chemistry.
Silver Compounds in Synthetic Chemistry. 1 A Facile Preparative Route for Pentafluorophenylsilver, AgC6F5 and its Use as an Oxidative Pentafluorophenyl Group Transfer Reagent in Reactions with Group 12 to 16 Elements — the Single Crystal Structure of AgC6F5 · EtCN, the First Arylsilver Derivative Crystallising in Infinite Chains
✍ Wieland Tyrra; Mathias S. Wickleder 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 2 views

AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c