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The thermolysis of organic and organometallic isocyanates. Evidence for metal-nitrene complexes and for nitrenoid decomposition in dimethylsulphoxide

โœ Scribed by R.A. Abramovitch; R.G. Sutherland; A.K.V. Unni

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
133 KB
Volume
13
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Only a few examples of the photochemical generation of nitrenes from isocyanates are known

(1) and it is reported that phenyl isocyanate is thermally stable even at 700" (2). In contrast

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โœ Natalie B. Feilchenfeld; Walter H. Waddell ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 411 KB

## Transxnt absorptton spectra nere recorded 1.5 ns to 6 ps foIlo\sing a 266 nm laser pulse for phenyl aide and for phenyl wxyanatc in aerated axtonttrilc and 3methylpentanc soluttons. Trnnsicnt spectra which are independent of concentra-Uon and of dsl;lv time. xc essentialI) tdenticti for plteny