Pulsed-laser kinetic evidence for an oscillating reaction in the photoiniated autocatalytic chain decomposition (pacd) reaction of phenyl azide and of phenyl isocyanate

Transient absorption spectral evidence f

Transient absorption spectral evidence for phenyl nitrene as the chain propagator in the photo-initiated autocatalytic chain decomposition of phenyl azide and phenyl isocyanate

✍ Natalie B. Feilchenfeld; Walter H. Waddell 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 411 KB

## Transxnt absorptton spectra nere recorded 1.5 ns to 6 ps foIlo\sing a 266 nm laser pulse for phenyl aide and for phenyl wxyanatc in aerated axtonttrilc and 3methylpentanc soluttons. Trnnsicnt spectra which are independent of concentra-Uon and of dsl;lv time. xc essentialI) tdenticti for plteny