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The Thermodynamically Stable Form of Solid Barbituric Acid: The Enol Tautomer

✍ Scribed by Prof. Dr. Martin U. Schmidt; Dr. Jürgen Brüning; Dr. Jürgen Glinnemann; Maximilian W. Hützler; Dipl.-Chem. Philipp Mörschel; Dr. Svetlana N. Ivashevskaya; Dr. Jacco van de Streek; Prof. Dario Braga; Dr. Lucia Maini; Dr. Michele R. Chierotti; Prof. Roberto Gobetto


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
565 KB
Volume
50
Category
Article
ISSN
0044-8249

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The reaction of barbituric acids with diazoalkanes (diazomethane and diazoethane) gives the N,N'dialkylbarbituric acids as the major products. Gas chromatograms of the reaction products show up to four additional Deaks. These have been shown bv mass and uroton magnetic resonance soectrometrv to be D