The thermodynamic properties of cerium sesquioxide, Ce 2 O 3 (s), have been measured. From the low-temperature adiabatic heat capacity measurements in the temperature range 3 K to 420 K, the values for โข mol -1 , respectively, have been obtained. The high-temperature enthalpy increment has been mea
The thermodynamic properties of Sr3MgSi2O8(s) fromT=(0 to 1500) K
โ Scribed by M.E. Huntelaar; A.S. Booij; E.H.P. Cordfunke; R.R. van der Laan
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 182 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-9614
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โฆ Synopsis
Ts4 to 420 K, yielding for C and Sะ at T s 298.15 K the values 257.35 " p . y1 . y1 . y1 . y1 .
ลฝ . 0.60 J K mol and 280.15 " 0.60 J K mol , respectively. The enthalpy increment function for temperatures above the ambient one has been obtained using high-temperature ลฝ . drop calorimetry measurements from T s 525 to 910 K. In addition, the standard molar enthalpy of formation has been derived from the standard molar enthalpies of solution in . y3 . y3 ลฝ . ลฝ . 3.1 mol dm HCl q 3.2 mol dm HF aq using an isoperibol solution calorimeter. From these measurements and the auxiliary data, the following value has been obtained: T . y1 ลฝ . ร ลฝ. 4 ลฝ . โฌH 298.15 K Sr MgSi O s s y 4575.3 " 5.1 kJ mol . A table containing the f m 3 2 8 ลฝ . thermodynamic properties at selected temperatures from 298.15 to 1500 K is provided. แฎ
๐ SIMILAR VOLUMES
The low-temperature adiabatic heat capacity of SrBaFe 4 O 8 (s) has been measured from T = 4 K to T = 420 K, yielding for C o p,m and S o m at T = 298.15 K, the values (288.9ยฑ0.3) J โข K -1 โข mol -1 and (338.0ยฑ0.3) J โข K -1 โข mol -1 , respectively. The enthalpy increment function for the above ambie
The standard molar enthalpies of formation of BaCeO s and SrCeO s have been derived 3 3 by combining the standard molar enthalpies of solution of the two compounds in . y3 . y3 ลฝ . ลฝ . 1.00 mol dm HCl q 0.10 mol dm KI aq obtained from literature, and measurements T ร . of auxiliary data. The followi
The temperature dependence of the standard molar heat capacity C o p,m of samples of crystalline tetraphenylphosphonium perchlorate and tetraphenylarsonium perchlorate was measured in an adiabatic low-pressure calorimeter between T = 4.8 K and T = 340 K and from T = 5.8 K to T = 340 K, respectively,