𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The thermodynamic properties of Ce2O3(s) fromT →  0 K to 1500 K

✍ Scribed by M.E. Huntelaar; A.S. Booij; E.H.P. Cordfunke; R.R. van der Laan; ; A.C.G. van Genderen; J.C. van Miltenburg

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
249 KB
Volume
32
Category
Article
ISSN
0021-9614

No coin nor oath required. For personal study only.

✦ Synopsis

The thermodynamic properties of cerium sesquioxide, Ce 2 O 3 (s), have been measured. From the low-temperature adiabatic heat capacity measurements in the temperature range 3 K to 420 K, the values for

• mol -1 , respectively, have been obtained. The high-temperature enthalpy increment has been measured in the temperature range 470 K to 883 K. The enthalpy of solution has been measured by using isoperibol solution calorimetry at T = 298.15 K in 0.250 mol • dm -3 HCl(aq). Using all available literature values, the standard molar enthalpy of formation has been derived: f H o m {Ce 2 O 3 (s), 298.15 K} = -(1812.4 ± 1.3) kJ • mol -1 . The thermodynamic properties have been calculated to T = 1500 K.

📜 SIMILAR VOLUMES

The thermodynamic properties ofSrBaFe4O8
The thermodynamic properties ofSrBaFe4O8(s)fromT →  0 toT =  1500 K
✍ M.E. Huntelaar; ; E.H.P. Cordfunke; ; G.D. Elzinga; R.R. van der Laan 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 159 KB

The low-temperature adiabatic heat capacity of SrBaFe 4 O 8 (s) has been measured from T = 4 K to T = 420 K, yielding for C o p,m and S o m at T = 298.15 K, the values (288.9±0.3) J • K -1 • mol -1 and (338.0±0.3) J • K -1 • mol -1 , respectively. The enthalpy increment function for the above ambie

Thermodynamic properties of tetraphenylp
Thermodynamic properties of tetraphenylphosphonium perchlorate and tetraphenylarsonium perchlorate fromT →  0 toT =  340 K
✍ B.V. Lebedev; N.N. Smirnova; L.Ya. Tsvetkova; Y. Marcus; G.T. Hefter 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 164 KB

The temperature dependence of the standard molar heat capacity C o p,m of samples of crystalline tetraphenylphosphonium perchlorate and tetraphenylarsonium perchlorate was measured in an adiabatic low-pressure calorimeter between T = 4.8 K and T = 340 K and from T = 5.8 K to T = 340 K, respectively,

Heat capacity and thermodynamic properti
Heat capacity and thermodynamic properties of GeSe2at temperatures fromT = ( 13 to 900) K. Structural phase transition atT =  423 K
✍ S. Stølen; H.-B. Johnsen; R. Abe; T. Atake; T. Grande 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 150 KB

The heat capacity of germanium diselenide GeSe 2 has been determined by adiabatic calorimetry at temperatures from (13 to 900) K. A phase transition not previously reported gives rise to a sharp λ-type heat capacity effect at T = 423 K. The overall estimated enthalpy of transition amounts to 1240 J•

Thermodynamic properties of (acetone&#xa
Thermodynamic properties of (acetone + methanol + 2-butanol ) atT = 298.15 K
✍ B. Orge; M. Iglesias; G. Marino; J. Tojo 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 174 KB

Densities and refractive indices for (acetone + methanol + 2-butanol) and the enclosed binary systems (acetone + 2-butanol) and (methanol + 2-butanol) have been measured at T = 298.15 K and atmospheric pressure. Values of densities, refractive indices, excess molar volumes, and changes of refractive

Heat capacities and entropies of La2O2CO
Heat capacities and entropies of La2O2CO3fromT =  (12 to 300)  K and of Nd2O2CO3fromT =  (12 to 930)  K, and their interpretation
✍ A. Olafsen; H. Fjellvåg; S. Sølen; T. Atake; H. Kawaji; K. Matsuo 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 213 KB

The heat capacities of La 2 O 2 CO 3 and Nd 2 O 2 CO 3 were determined by adiabatic shield calorimetry from T = (12 to 300) K and T = (12 to 930) K, respectively. For the dineodymium dioxide carbonate a Schottky-type heat capacity with maximum near T = 60 K was observed. The transition is due to spl