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The thermal decarboxylation of sodium trichloroacrylate in an aprotic medium

✍ Scribed by W. M. Wagner; Miss L. Vriesman; H. Kloosterziel; A. F. Bickel

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
180 KB
Volume
82
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Sodium trichloroacrylate decomposes in 1,2‐dimethoxyethane at 90° to give quantitative yields of CO~2~ and NaCl. Evidence is presented that this decarboxylation involves the trichlorovinyl anion, CCl~2~CCl^−^, as an intermediate.

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The thermal decarboxylation of alkali tr
The thermal decarboxylation of alkali trichloroacetates in aprotic solvents III
✍ W. M. Wagner; H. Kloosterziel; A. F. Bickel 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 318 KB

## Abstract Thermal decomposition of sodium trichloroacetate in 1,2‐dimethoxyethane in the presence of various perchloro compounds leads to α,β‐elimination of chlorine from these compounds and formation of CCl~4~. Hexachlorocyclopentadiene yields decachlorobi‐(2,4‐cyclopentadien‐1‐yl) These result

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## Abstract The thermal decarboxylation of alkali trichloroacetates in aprotic solvents in the presence of olefins has been investigated. The isolation of dichlorocyclopropanes in good yields demonstrates the formation of CCl~2~ as an intermediate. By this method, the reaction of base‐sensitive acc