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The thermal decarboxylation of alkali trichloroacetates in aprotic solvents III

✍ Scribed by W. M. Wagner; H. Kloosterziel; A. F. Bickel

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
318 KB
Volume
81
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Thermal decomposition of sodium trichloroacetate in 1,2‐dimethoxyethane in the presence of various perchloro compounds leads to α,β‐elimination of chlorine from these compounds and formation of CCl~4~. Hexachlorocyclopentadiene yields decachlorobi‐(2,4‐cyclopentadien‐1‐yl)

These results point to a mechanism involving Cl^+^‐abstraction by the CCl~3~^−^ion.

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