The theory of intensities in the infrared spectra of polyatomic molecules
β Scribed by L.A. Gribov; N.I. Prokofieva
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 765 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0022-2860
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A theory of the dissociation of polyatomic molcculcs by intense infrared kscr radiation is prescntcd. It is suggested that vibrational heating of the whole molecule occurs by intramolecular vIbrationa coupling to a given infrared active mode which is in near-rcsomince with the applied field. A high-
The effect of the noncorrespondence of normal coordinates on the Franck-Condon factors governing the appearance of non-totally symmetric vibrations in electronic spectra is examined. In a two-dimensional symmetry species containing vibrations 1 and 2, transitions such as 1 1 0 2 1 0 , 1 1 0 2 3 0 ,