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The tetrafluoronitronium(V) cation, NF4+

โœ Scribed by Karl O Christe; Jacques P Guertin; Attila E Pavlath


Book ID
103108763
Publisher
Elsevier Science
Year
1966
Weight
124 KB
Volume
2
Category
Article
ISSN
0020-1650

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Cation distributions and values of the oxygen parameter in the spinel ph-of mixed vanadium oxides with the general formula LizMeV2-,04, where Me is Zn or Mg, respectively, were studied by X-ray diffraction measurements. The distribution of cations on the sublattices in the zinc series can be. expres

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NFdAsFe decomposes smoothly at 175" and above, to the starting materials NF,, F2 and AsFs. The decomposition has been followed by total pressure measurements and found to obey the equation ## P312 = At + B This has been interpreted in terms of an equilibrium dissociation step NF4AsF6 + NF, + AsFs