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The temperature characteristics of an H2S-sensitive Pd-gate MOS transistor

✍ Scribed by Zhang Weixin; Zhao Yibing


Publisher
Elsevier Science
Year
1988
Weight
642 KB
Volume
15
Category
Article
ISSN
0250-6874

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An alternative mechanism of BH2SH format
✍ Alexander M. Mebel; Djamaladdin G. Musaev; Keiji Morokuma πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 411 KB

An alternative mechanism of mercaptoborane, BH,SH, formation is proposed for the reaction of BzHs with SH2. It involves concerted elimination of BH3 and H2 from the H2SB2Hs complex and the highest energy on the pathway relative to SH, + B2H6 is 27.4 kcal/mol at MP4(SDTQ)/6-31 +G(2d, p)//MP2(FULL)/6\