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The T3 (π, π) State of acridine

✍ Scribed by N. Periasamy

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 359 KB
Volume: 99
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87549-6

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✦ Synopsis

The O-O band maGmum of the transition T3(n, r*) .-T1 (n, n*) of acridine occurs at = 10200 + 20 cm-' in inert (nhcxme. benzene. Ccl& at 10220 2 20 cm -I in polar (acetonitrile) and St 10170 i 50 cm-1 in hydrogen-bonding, (methanol, 2propanol and alkaline lvater) solsents. Based on the solvent-independent energy of Tl(n, n*). the Ts(a, n*) state of acridine is estimated at 26050 k 50 cm-' in all the solvents.

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