The system titanium-sulfur. I: The structure of Ti5S8 and the unit cells of Ti3S4 and Ti4S5
โ Scribed by E. Flink; G. A. Wiegers; F. Jellinek
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 190 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0165-0513
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๐ SIMILAR VOLUMES
The new compounds La 4 Ti 2 O 4 Se 5 and La 6 Ti 3 O 5 Se 9 have been obtained from stoichiometric reactions of La, Ti, TiO 2 , and Se in fused-silica tubes at 1223 K. Potassium halide 6uxes were used to promote the crystallization. The compounds have been characterized by single-crystal X-ray di4ra
The compound Na 5 Li 3 Ti 2 S 8 has been synthesized by the reaction of Ti with a Na/Li/S flux at 723 K. Na 5 Li 3 Ti 2 S 8 crystallizes in a new structure type with four formula units in space group C2/c of the monoclinic system. The structure contains three crystallographically independent Na + ca