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The site distribution of Ti and V and the metal-metal interaction in the ternary system (V,Ti)5S8

✍ Scribed by Hiroshi Nozaki; Masanobu Saeki; Mitsuko Onoda; Yoshito Onoda


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
484 KB
Volume
46
Category
Article
ISSN
0022-4596

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Influence of the Metal–Metal Sigma Bondi
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chains of Sr 9/8 TiS 3 and Sr 8/7 TiS 3 contain oligomer units (Oh) n (n ‫؍‬ 4, 5) made up of face-sharing TiS 6 octahedra (Oh). Given the (TiS 3 ) chains aligned along the z direction, the only occupied d-block levels of each (TiS 3 ) chain are the most sigma bonding level of each (Oh) n oligomer,