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The synthesis ofO-substituted 3-oximes of 6α -methyl-16α,17α-cyclohexanopregn-4-ene-3,20-diones tritium-labeled in the 1,2-position

✍ Scribed by V. P. Shevchenko; I. Yu. Nagaev; I. S. Levina; L. E. Kulikova; N. F. Myasoedov; A. V. Kamernitzky


Book ID
111457074
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
207 KB
Volume
36
Category
Article
ISSN
1068-1620

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✍ I. S. LEVINA; A. V. KAMERNITSKII 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Synthesis of 6α-Methyl-16α,17α-cyclohexanoprogesterone via γ-Methylenation of 16α,17. alpha.-Cyclohexanopregn-4-ene-3,20-dione. -An improved synthetic way to the title cyclohexanoprogesterone (IV) is presented. The introduction of the 6α-methyl group is achieved by regioselective γ-methylenation of