The synthesis of γ-amino olefins. A novel intramolecular aziridine — allylsilane reaction
✍ Scribed by Stephen C. Bergmeier; Punit P. Seth
- Book ID
- 103408623
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 264 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The Lewis acid mediated cyclization of y-oxygen substituted allylic stannane 1, having a chiral imine group at the terminus of the carbon chain, afforded trans ~amino cyclic ether 2 with very high to good diastereoselectivities in high chemical yields.
## Abstract The stereochemical aspects of the intramolecular __Ramberg__‐__Bäcklund__ reaction, __i.e.__ the 1,3‐elimination of hydrogen halide followed by sulfur dioxide extrusion, have been studied on the α‐bromosulfones of the 1‐thiadecalinThroughout this paper ‘1‐thiadecalin’ will be used in pl