✦ LIBER ✦

Asymmetric synthesis of β-amino cyclic ethers via the intramolecular reaction of γ-alkoxyallylstannane with chiral imine

✍ Scribed by Jung-Youl Park; Choul-Hong Park; Isao Kadota; Yoshinori Yamamoto

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 234 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10866-8

No coin nor oath required. For personal study only.

✦ Synopsis

The Lewis acid mediated cyclization of y-oxygen substituted allylic stannane 1, having a chiral imine group at the terminus of the carbon chain, afforded trans ~amino cyclic ether 2 with very high to good diastereoselectivities in high chemical yields.

📜 SIMILAR VOLUMES

ChemInform Abstract: Asymmetric Synthesi

ChemInform Abstract: Asymmetric Synthesis of β-Amino Cyclic Ethers via the Intramolecular Reaction of γ-Alkoxyallylstannane with Chiral Imine.

✍ J.-Y. PARK; C.-H. PARK; I. KADOTA; Y. YAMAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

ChemInform Abstract: Diastereo- and Enan

ChemInform Abstract: Diastereo- and Enantioselective Synthesis of β-Amino Cyclic Ethers via the Intramolecular Reaction of γ-Alkoxyallylstannane with Imine.

✍ Jung-Youl Park; Isao Kadota; Yoshinori Yamamoto 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 1 views

Facile Asymmetric Synthesis of Aziridine

Facile Asymmetric Synthesis of Aziridine Derivatives via the Diastereoselective Reaction of Chiral Imines with Dimethylsulfonium Methylide.

✍ Kimio Higashiyama; Masataka Matsumura; Ayako Shiogama; Takayasu Yamauchi; Sigeru 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 119 KB

Synthesis of Enantiomerically Enriched β

Synthesis of Enantiomerically Enriched β-Amino Alcohol Derivatives via Chiral Base Mediated-Asymmetric Deprotonation of (Benzyl Methyl Ether) Tricarbonylchromium(0) Complex and Electrophilic Trapping with Imines.

✍ Cui-Hua Zhao; Li Liu; Yong-Jun Chen; Dong Wang 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 22 KB 👁 1 views

Practical Asymmetric Synthesis of β-Tric

Practical Asymmetric Synthesis of β-Trichloromethyl-β-hydroxy Ketones by the Reaction of Chloral or Chloral Hydrate with Chiral Imines.

✍ Kazumasa Funabiki; Norihiro Honma; Wataru Hashimoto; Masaki Matsui 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 134 KB

Asymmetric synthesis of monocyclic β-lac

Asymmetric synthesis of monocyclic β-lactams: application of imines derived from chiral N-protected α-amino aldehydes in the staudinger reaction

✍ Claudio Palomo; Fernando P. Cossío; Carmen Cuevas 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 151 KB