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THE SYNTHESIS OF β- D -GLUCOPYRANOSYL 2-DEOXY-α- D - ARABINO -HEXOPYRANOSIDE

✍ Scribed by Lemieux, R. U.; Morgan, A. R.

Book ID
120985385
Publisher
NRC Research Press
Year
1965
Tongue
French
Weight
470 KB
Volume
43
Category
Article
ISSN
0008-4042

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Stereoselective Synthesis of 2-Deoxy-α-D-arabino-hexopyranosides of Triterpenic Alcohols. -The stereoselective glycosylation of triterpenic alcohols (cf. (II)) by glycal (I) is achieved in the presence of NIS as promotor. Deiodination by catalytic hydrogenation of the obtained glycosides (cf. (III)