𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Stereoselective Synthesis of 2-Deoxy-α-D-arabino-hexopyranosides of Triterpenic Alcohols.

✍ Scribed by L. A. BALTINA; O. B. FLEKHTER; E. V. VASIL'EVA; G. A. TOLSTIKOV

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Stereoselective Synthesis of 2-Deoxy-α-D-arabino-hexopyranosides of Triterpenic Alcohols.

-The stereoselective glycosylation of triterpenic alcohols (cf. (II)) by glycal (I) is achieved in the presence of NIS as promotor. Deiodination by catalytic hydrogenation of the obtained glycosides (cf. (III)) and subsequent deacetylation gives the corresponding 2-deoxy-hexopyranosides of glycyrrhetic acid (cf. (V)).

📜 SIMILAR VOLUMES

ChemInform Abstract: Highly Stereoselect
ChemInform Abstract: Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides.
✍ Halszka Bielawska; Maria Michalska 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides. -Using S-(2-deoxyglycosyl)phosphorodithioates such as (I) as glycosyl donors allows a highly diastereoselective synthesis of 2-deoxyα-glycosides [cf. (III)] and α-disaccharides such as (V). -(BIELAWSKA,