The synthesis of α, β-unsaturated aldehydes by one-carbon homologation of carbonyl compounds
✍ Scribed by Vichai Reutrakul; Wipa Kanghae
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 152 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
l'he synthesis of (z, &unsaturated aldehydes has been a focus of current interest'. However there are only few methods for the syntheses of a, B-unsaturated aldehydes hy one-carbon homclogation'. We wish to report a convenient synthesis of the 1-alkenecarboxaldehydes from the corresponding carbonyl compounds (equation 1).
📜 SIMILAR VOLUMES
The alkylation of enone with 1-chloroalkyl phenyl sulfoxide followed by treatment with thiophenolate afforded s-phenylthio-8,y-unsaturated car-bony1 compound, which was oxidized and then hydrolyzed to give a,8-unsaturated y-hydroxy carbonyl compound in good yield. Highly oxygenated ketones and aldeh
## Abstract For Abstract see ChemInform Abstract in Full Text.