## Substituents have been found to have a marked influence on the metastable ion decompositions and collisionally activated (CA) fragmentations of the M" ion of a number of 1,2,3-triarylpropen-l-ones. An attempt has been made to confirm the structures of the rearrangement ions, IC,,H,,I+\*, [C13Hl
โฆ LIBER โฆ
The synthesis of two 3,3,3-triarylpropenes and two 2-methyl-3,3,3-triarylpropenes
โ Scribed by Norman, R. O. C.; Thomas, C. B.
- Book ID
- 111962218
- Publisher
- The Royal Society of Chemistry
- Year
- 1967
- Tongue
- English
- Weight
- 876 KB
- Volume
- 0
- Category
- Article
- ISSN
- 0022-4952
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3-Methyl-1,2,4-benzotriazine and some of its derivatives were prepared in moderate yields (50-70%) via a reductive cyclization by a PtO 2catalyzed hydrogenation of the corresponding 2nitrophenylhydrazones of the pyruvic acid. The latter compounds were obtained in yields higher than 90% by reacting 2