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The Synthesis of Some 4-Alken-1-ols 1

✍ Scribed by Brandon, Richard C.; Derfer, John M.; Boord, Cecil E.


Book ID
126172805
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
379 KB
Volume
72
Category
Article
ISSN
0002-7863

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✍ Adiwidjaja, Gunadi ;Flörke, H. ;Kirschning, A. ;Schauman, Ernst 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 855 KB

## Abstract Silyl‐substituted 4‐alken‐1‐ols cyclize in the presence of a wide range of electrophilic reagents to give substituted tetra‐hydrofurans. The silyl group accelerates ring closure by its β‐effect and its position determines the efficiency of stereo‐control. Thus, a vinylic silyl group as