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Pheromone synthesis via organoboranes: a stereospecific synthesis of (Z)-7-alken-1-ols

โœ Scribed by Basavaiah, D.; Brown, Herbert C.


Book ID
125481710
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
249 KB
Volume
47
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Organoboranes for synthesis. 7. An impro
โœ Herbert C Brown; Kee-Won Kim; Morris Srebnik; Singaram Bakthan ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 665 KB

Trforganylboranes, R3B, and diorganylborinic esters, R2BOR', re--readily with preformed chloramine or hydroxylamine-0-sulfonic acid to produce the corresponding primary amines, RNH2. However, the product of the reaction following hydrolysis is the boronic acid, RB(oH)2, limiting the yield to 67% for