The synthesis of novel polycyclic heterocyclic ring systems via photocyclization. 22 Dibenzo[f,h]benzothieno[2,3-c]quinoline, dibenzo[f,h]benzothieno[2,3-c][1,2,4]triazolo[4,3-a]quinoline and dibenzo[f,h]naphtho[2′,1′:4,5]thieno[2,3-c]quinoline
✍ Scribed by Jiann-Kuan Luo; Maria P. Cabal; Ronald F. Federspiel; Raymond N. Castle
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 325 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
Photocyclization of 3‐chloro‐N‐(9‐phenanthryl)benzo[b]‐thiophene‐2‐carboxamide (3) and 3‐chloro‐N‐(9‐phenanthryl)‐naphtho[1,2‐b]thiophene‐2‐carboxamide (10) yielded dibenzo[f,h]benzothieno[2,3‐c]‐quinolin‐10(9__H__)‐one (4) and dibenzo[f,h]naphtho[2′,1′:4,5]thieno[2,3‐c]quinolin‐10(9__H__)‐one (11), respectively. Further elaboration of the lactams provided three novel unsubstituted new ring systems.
📜 SIMILAR VOLUMES
## Abstract Photocyclization of 3‐chloro‐N‐(3‐phenanthryl)thieno[2,3‐__b__]thiophene‐2‐carboxamide (5) yielded only one of the two possible structural isomers, thieno[3′,2′:4,5]thieno[2,3‐__c__]naphtho[1,2‐__f__]quinolin‐6(5__H__)‐one (6), which was further elaborated to afford the unsubstituted ri
## Abstract Four previously unknown polycyclic heterocyclic ring systems, namely, benzo[__h__]thieno[3′,2′:4,5]‐thieno[2,3‐__c__]quinoline (6), benzo[__h__]thieno[3′,2′:4,5]thieno[2,3‐__c__]quinoline (11), benzo[__f__]thieno‐[3′,2′:4,5]thieno[2,3‐__c__]tetrazolo[1,5‐__a__]quinoline (12) and benzo[_
## Abstract Photocyclization of 3‐chloro‐__N__‐(3‐phenanthryl)naphtho[1,2‐__b__]thiophene‐2‐carboxamide (**12**) furnished only one of the two possible isomers, __i.e.__, naphtho[2′,1′:4,5]thieno[2,3‐__c__]naphtho[1,2‐__f__]quinolin‐6(5__H__)‐one (**13**), which was further elaborated to yield the
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