The synthesis of novel polycyclic heterocyclic ring systems via photocyclization. 20. Benzo[h]thieno[3′,2′:4,5]thieno[2,3-c]-quinoline, benzo[f]thieno[3′,2′:4,5]thieno[2,3-c]quinoline, benzo[f]thieno[3′,2′:4,5]thieno[2,3-c]tetrazolo[1,5-a]quinoline and benzo[f]thieno[3′,2′:4,5]thieno[2,3-c][1,2,4]triazolo[4,3-a]quinoline
✍ Scribed by Jiann-Kuan Luo; Ronald F. Federspiel; Raymond N. Castle
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 347 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
Four previously unknown polycyclic heterocyclic ring systems, namely, benzo[h]thieno[3′,2′:4,5]‐thieno[2,3‐c]quinoline (6), benzo[h]thieno[3′,2′:4,5]thieno[2,3‐c]quinoline (11), benzo[f]thieno‐[3′,2′:4,5]thieno[2,3‐c]tetrazolo[1,5‐a]quinoline (12) and benzo[f]thieno[3′,2′:4,5]thieno[2,3‐c][1,2,4]‐triazolo[4,3‐a]quinoline (13), were synthesized via oxidative photocyclization. Unequivocal total assignments of the proton and carbon nmr spectra of 6 and 11 were made through the concerted usage of COSY, HMQC and HMBC two‐dimensional nmr spectroscopic methods.
📜 SIMILAR VOLUMES
## Abstract Photocyclization of 3‐chloro‐N‐(3‐phenanthryl)thieno[2,3‐__b__]thiophene‐2‐carboxamide (5) yielded only one of the two possible structural isomers, thieno[3′,2′:4,5]thieno[2,3‐__c__]naphtho[1,2‐__f__]quinolin‐6(5__H__)‐one (6), which was further elaborated to afford the unsubstituted ri
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract Photocyclization of 3‐chloro‐__N__‐(3‐phenanthryl)naphtho[1,2‐__b__]thiophene‐2‐carboxamide (**12**) furnished only one of the two possible isomers, __i.e.__, naphtho[2′,1′:4,5]thieno[2,3‐__c__]naphtho[1,2‐__f__]quinolin‐6(5__H__)‐one (**13**), which was further elaborated to yield the
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v