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The synthesis of novel polycyclic heterocyclic ring systems. 3. Synthesis and NMR spectroscopy of 15-chloro[1]benzo-thieno[2″,3″:3′,4′]naphtho[1′,2′:4,5]thieno[2,3-c]quinoline

✍ Scribed by Kenji Sasaki; Osamu Tokuda; Takashi Hirota; Jiann-Kuan Luo; Ronald F. Federspiel; Raymond N. Castle


Publisher
Journal of Heterocyclic Chemistry
Year
1997
Tongue
English
Weight
305 KB
Volume
34
Category
Article
ISSN
0022-152X

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## Abstract Four previously unknown polycyclic heterocyclic ring systems, namely, benzo[__h__]thieno[3′,2′:4,5]‐thieno[2,3‐__c__]quinoline (6), benzo[__h__]thieno[3′,2′:4,5]thieno[2,3‐__c__]quinoline (11), benzo[__f__]thieno‐[3′,2′:4,5]thieno[2,3‐__c__]tetrazolo[1,5‐__a__]quinoline (12) and benzo[_

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## Abstract Photocyclization of 3‐chloro‐N‐(3‐phenanthryl)thieno[2,3‐__b__]thiophene‐2‐carboxamide (5) yielded only one of the two possible structural isomers, thieno[3′,2′:4,5]thieno[2,3‐__c__]naphtho[1,2‐__f__]quinolin‐6(5__H__)‐one (6), which was further elaborated to afford the unsubstituted ri

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## Abstract Photocyclization of 3‐chloro‐__N__‐(3‐phenanthryl)naphtho[1,2‐__b__]thiophene‐2‐carboxamide (**12**) furnished only one of the two possible isomers, __i.e.__, naphtho[2′,1′:4,5]thieno[2,3‐__c__]naphtho[1,2‐__f__]quinolin‐6(5__H__)‐one (**13**), which was further elaborated to yield the