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The Synthesis of New HetPHOX Ligands and Their Application to the Intermolecular Asymmetric Heck Reaction

✍ Scribed by Martin O. Fitzpatrick; Helge Muller-Bunz; Patrick J. Guiry


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
336 KB
Volume
2009
Category
Article
ISSN
1434-193X

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New Thiazoline–Oxazoline Ligands and The
✍ Seán C. McKeon; Helge Müller-Bunz; Patrick J. Guiry 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB

## Abstract Six members of a novel non‐__C__~2~‐symmetric ligand class incorporating an oxazoline and thiazoline unit have been prepared in a four‐step, high‐yielding and convergent synthesis, in which the key step is a microwave‐assisted palladium‐catalyzed aryl amination. The new ligands induced