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The synthesis of new bis/mono fluorinated sultones and their derivatives

โœ Scribed by J. Mohtasham; D.G. Cox; D.J. Burton; G.L. Gard


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
685 KB
Volume
42
Category
Article
ISSN
0022-1139

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โœฆ Synopsis


The fluorinated his/mono B-sultones, [cF~(~o~)cF~I~ and CF2=CF(CF2)*CF(~O2)CF2(~), 1, and 2, are formed via the reaction of sulfur trioxide with 1,5-perfluorohexadiene. In the presence of NaF, 2 z and $ rearranged to give the isomeric products, CF2=CF(CF2)2CF(SO2F)C(O)F and [FC(O)CF(S02F)CF2]2, respectively. New sulfonyl fluoride sultones $ and ,2;

achieved.


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