## Abstract Convenient procedures for the synthesis of new organophosphorusโsubstituted monoโ and bis(trimethylsilyl)amines with PCH~2~N moiety are proposed, starting from trimethylsilyl esters of organophosphorus acids, as well as 1,3,5โtrialkylhexahydroโ1,3,5โtriazines and __N__โalkoxymethyl bis(
The synthesis of new bis/mono fluorinated sultones and their derivatives
โ Scribed by J. Mohtasham; D.G. Cox; D.J. Burton; G.L. Gard
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 685 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-1139
No coin nor oath required. For personal study only.
โฆ Synopsis
The fluorinated his/mono B-sultones, [cF~(~o~)cF~I~ and CF2=CF(CF2)*CF(~O2)CF2(~), 1, and 2, are formed via the reaction of sulfur trioxide with 1,5-perfluorohexadiene. In the presence of NaF, 2 z and $ rearranged to give the isomeric products, CF2=CF(CF2)2CF(SO2F)C(O)F and [FC(O)CF(S02F)CF2]2, respectively. New sulfonyl fluoride sultones $ and ,2;
achieved.
๐ SIMILAR VOLUMES
## Abstract Convenient procedures for the synthesis of functionalized monoโ and bisorganophosphorus acids and their derivatives with unsaturated and aromatic fragments, starting from the available derivatives of trivalent phosphorus acids, unsaturated and aromatic aldehydes, and carboxylic acid chl